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You see a hot girl and say 'I'd poop on it' because she's so attractive you'd poop on her just to get in her pants. You're treating her like a piece of trash, not a person.
My crush walked by and I said 'I'd poop on it' and then ran away like a coward.
He said 'I'd poop on it' when he saw the new girl in class. She stared at him like he was insane.
I told my friend 'I'd poop on it' when I saw his ex. He laughed and said I was crazy.