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This phrase is usually said by pot-heads and people who think they're cool, but it really means they want to take you on a wild trip with drugs or something stupid.
'I'd love to turn you on, loser, let's smoke this blunt and forget we ever existed.'
'Bro, I'd love to turn you on, but you're too high to even stand up.'
'If you don't come with me, I'll turn you on by force.'